Importance of geochemical transformations in determining submarine groundwater discharge-derived trace metal and nutrient fluxes

Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO₃, PO₄, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO₄ and NO₃ (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 10²– 8.2 × 10³ μmol d⁻¹). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 10³ μmol d⁻¹ (inland, freshwater well) vs. 2.1 × 10⁵ μmol d⁻¹(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.     

A new method for the quantification of different redox-species of molybdenum (V and VI) in seawater

A new method for the direct determination of reduced and oxidized Mo species (Mo (V) and Mo (VI)) in seawater was developed and used for the first time. The method includes the complexation of Mo (V) with tartrate, solid phase extraction of the Mo (V)–tartrate complex by a XAD 7HP resin, followed by elution with acidic acetone. In this study, the eluted Mo (V) was quantified by graphite furnace atomic absorption spectrometry. The detection limit of this protocol was on the order of 0.2 nM. The analytical precision was 10% of ~ 10 nM. This method was successfully applied to the determination of Mo (V) and Mo (VI) in surface and bottom waters at the head of Peconic River Estuary. Total Mo (Mo (V) + Mo (VI)) ranged from 100–120 nM in most bottom saline waters, and 2.5–15 nM for surface fresher waters. Concentrations of Mo (V) in these environments ranged from 0 nM to ~ 15 nM, accounting for 0%–15% of the total dissolved Mo pool. The time series experiments showed that the Mo speciation changed within 1 h after the water collection, and therefore it is strongly suggested that speciation analysis be carried out within the first 15 min. However, since these are the first Mo speciation data in concentration ranges typical of normal marine and coastal waters, additional research may be required to optimize the methodology and further explore Mo cycling mechanisms.     

ISA accelerometer onboard the Mercury Planetary Orbiter: error budget

We have estimated a preliminary error budget for the Italian Spring Accelerometer (ISA) that will be allocated onboard the Mercury Planetary Orbiter (MPO) of the European Space Agency (ESA) space mission to Mercury named BepiColombo. The role of the accelerometer is to remove from the list of unknowns the non-gravitational accelerations that perturb the gravitational trajectory followed by the MPO in the strong radiation environment that characterises the orbit of Mercury around the Sun. Such a role is of fundamental importance in the context of the very ambitious goals of the Radio Science Experiments (RSE) of the BepiColombo mission. We have subdivided the errors on the accelerometer measurements into two main families: (i) the pseudo-sinusoidal errors and (ii) the random errors. The former are characterised by a periodic behaviour with the frequency of the satellite mean anomaly and its higher order harmonic components, i.e., they are deterministic errors. The latter are characterised by an unknown frequency distribution and we assumed for them a noise-like spectrum, i.e., they are stochastic errors. Among the pseudo-sinusoidal errors, the main contribution is due to the effects of the gravity gradients and the inertial forces, while among the random-like errors the main disturbing effect is due to the MPO centre-of-mass displacements produced by the onboard High Gain Antenna (HGA) movements and by the fuel consumption and sloshing. Very subtle to be considered are also the random errors produced by the MPO attitude corrections necessary to guarantee the nadir pointing of the spacecraft. We have therefore formulated the ISA error budget and the requirements for the satellite in order to guarantee an orbit reconstruction for the MPO spacecraft with an along-track accuracy of about 1 m over the orbital period of the satellite around Mercury in such a way to satisfy the RSE requirements.     

Geochemical arguments for identifying second‐order sea‐level changes in hemipelagic carbonate ramp deposits

Second‐order transgressive–regressive (T–R) cycles, previously recognized using sedimentological criteria in Lower Jurassic hemipelagic deposits from northern Spain, are distinguishable based upon bulk‐rock organic geochemistry [total organic carbon (TOC) and hydrogen index (HI)] and the stable carbon isotope compositions from belemnite rostra. There is a coincidence between regressions and decreasing δ¹³C_bel, TOC and HI values, and between transgressions and increasing δ¹³C_bel, TOC and HI values. The δ¹⁸O and Mg/Ca records from the belemnite rostra are not always in phase with the T–R cycles. The δ¹⁸O_bel record reveals, however, a prominent excursion towards higher values within the spinatum Zone that correlates, according to our results, with a regression and with negative shifts in Mg/Ca, δ¹³C_bel and TOC. On the other hand, an excursion in the δ¹⁸O_bel towards lower values in the serpentinus Zone also correlates with a peak transgression and with positive shifts in Mg/Ca, δ¹³C_bel and TOC. These two excursions have been identified in other European regions as geochemical perturbations of the same characteristics. This suggests a link between second‐order relative sea‐level changes and variations in seawater geochemistry that may reflect local and regional palaeoceanographic perturbations in sea‐water temperature, salinity and water circulation during the Early Jurassic. Terra Nova, 18, 233–240, 2006     

POLARIX: a pathfinder mission of X-ray polarimetry

Since the birth of X-ray astronomy, spectral, spatial and timing observation improved dramatically, procuring a wealth of information on the majority of the classes of the celestial sources. Polarimetry, instead, remained basically unprobed. X-ray polarimetry promises to provide additional information procuring two new observable quantities, the degree and the angle of polarization. Polarization from celestial X-ray sources may derive from emission mechanisms themselves such as cyclotron, synchrotron and non-thermal bremsstrahlung, from scattering in aspheric accreting plasmas, such as disks, blobs and columns and from the presence of extreme magnetic field by means of vacuum polarization and birefringence. Matter in strong gravity fields and Quantum Gravity effects can be studied by X-ray polarimetry, too. POLARIX is a mission dedicated to X-ray polarimetry. It exploits the polarimetric response of a Gas Pixel Detector, combined with position sensitivity, that, at the focus of a telescope, results in a huge increase of sensitivity. The heart of the detector is an Application-Specific Integrated Circuit (ASIC) chip with 105,600 pixels each one containing a full complete electronic chain to image the track produced by the photoelectron. Three Gas Pixel Detectors are coupled with three X-ray optics which are the heritage of JET-X mission. A filter wheel hosting calibration sources unpolarized and polarized is dedicated to each detector for periodic on-ground and in-flight calibration. POLARIX will measure time resolved X-ray polarization with an angular resolution of about 20 arcsec in a field of view of 15 × 15 arcmin and with an energy resolution of 20% at 6 keV. The Minimum Detectable Polarization is 12% for a source having a flux of 1 mCrab and 10⁵ s of observing time. The satellite will be placed in an equatorial orbit of 505 km of altitude by a Vega launcher. The telemetry down-link station will be Malindi. The pointing of POLARIX satellite will be gyroless and it will perform a double pointing during the earth occultation of one source, so maximizing the scientific return. POLARIX data are for 75% open to the community while 25% + SVP (Science Verification Phase, 1 month of operation) is dedicated to a core program activity open to the contribution of associated scientists. The planned duration of the mission is one year plus three months of commissioning and SVP, suitable to perform most of the basic science within the reach of this instrument. A nice to have idea is to use the same existing mandrels to build two additional telescopes of iridium with carbon coating plus two more detectors. The effective area in this case would be almost doubled.     

Landslide susceptibility and hazard assessment in San Ramón Ravine, Santiago de Chile, from an engineering geological approach

Debris flows and soil and rock slides are among the main geological hazards in the mountain foothills of Central Chile. Geological risk associated with the development of landslides, especially debris flows triggered in the basins of ravines that drain into the capital city, Santiago, has increased in time due to accelerated urban expansion. A landslide hazard evaluation in the San Ramón Ravine, located within the foothills of Santiago is presented. Hazard evaluation is based on a methodology that combines the determination of landslide susceptibility calculated by integration of conditioning factors, with the assessment of slope failure and runout probabilities incorporating geotechnical engineering approaches. The methodology is appropriate for medium or subregional scale studies with limited data. The results show that in San Ramón Ravine the landslide hazard consists mainly of debris flows, rock block slides, rock falls and shallow soil slides. Among these, debris flows are the most important due to the urban area that can be affected. Other case studies show that the method can be used in other regions with minor adaptations for territorial planning or for engineering and environmental purposes.     

Recent Changes Occurred in the Terminus of the Debris-covered Bilafond Glacier in the Karakoram Himalayas Using Remotely Sensed Images and Digital Elevation Models (1978-2011)

Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM＋ images were used for this study. Digital elevation models derived from ASTER GDEM and SRTM were also utilized. Visible, infrared and thermal infrared channels were utilized in order to get accurate glacier change maps. Three methods were tried to map this debris-covered glacier in this research. The glacier has been mapped successfully and the changes in the glacier terminus from 1978 to 2011 have been calculated. Manual, semi-automatic and thermal methods were found to give similar results. It was found that the glacier has undergone serious ablation during this period despite of the fact that many of the larger glaciers in the Hindu Kush and Karakoram mountain regions in the Upper Indus Basin were reported to be expanding. The terminus has been moved back about 600 meters during this period and there was an abrupt change in the glacier terminus during 1990-2002. We propose that debris thickness is not the only factor that influences the glacier ablation but the altitude of the debris-covered glacier as well. Many glaciers in the Karakoram region reported to be expanding were having higher altitudes compared to the study area.     

The recording of floods and earthquakes in Lake Chichój,Guatemala during the twentieth century

Laguna Chichój (Lake Chichój) is the only deep permanent lake in the central highlands of Guatemala. The lake is located in the boundary zone between the North American and Caribbean plates. The lake has been struck by devastating earthquakes and tropical cyclones in historical times. We investigated the imprint of twentieth century extreme events on the sedimentary record of this tropical lake using a bathymetric survey of the lake, coring the lake floor, and providing a chronology of sediment accumulation. The lake occupies a series of circular depressions likely formed by the rapid dissolution of a buried body of gypsum. ²¹⁰Pb and ¹³⁷Cs inventories and varve counting indicate high rates of sedimentation (1–2 cm year^?1). The annually layered sediment is interrupted by turbidites of two types: a darker-colored turbidite, enriched in lake-derived biogenic constituents, and interpreted as a seismite, and a lighter-colored type, enriched in catchment-derived constituents, interpreted as a flood layer. Comparison of our ¹³⁷Cs-determined layer ages with a catalog of twentieth century earthquakes shows that an earthquake on the Motagua fault in 1976 generated a conspicuous darker-colored turbidite and slumped deposits in separate parts of the lake. The entire earthquake inventory further reveals that mass movements in the lake are triggered at Modified Mercalli Intensities higher than V. Tropical cyclonic depressions known to have affected the lake area had limited effect on the lake, including Hurricane Mitch in 1998. One storm however produced a significantly thicker flood layer in the 1940s. This storm is reportedly the only event to have generated widespread slope failures in the lake catchment. It is thus inferred that abundant landsliding provided large amounts of concentrated sediment to the lake, through hyperpycnal flows.     

Land use dynamics in Brazilian La Plata Basin and anthropogenic climate change

The La Plata Basin (LPB) is one of the most important regions for agriculture and livestock production in South America, playing a central role in the world food production and food security. Within its borders is also located the whole Brazilian Pantanal region. Identifying the most important land use sectors in LPB as well as the changes observed in the past years is fundamental to recognize which areas of the basin might be more vulnerable to climate change in order to design adaptation strategies. A general characterization of land use and livestock production of Brazilian LPB was done by using the System of Automatic Retrieving (SIDRA) of Brazilian Institute of Geography and Statistics (IBGE) platform as the major source of data. It was observed expressive increases in land areas used for temporary crops, such as soybean, sugarcane, and maize, as well as increases in poultry and swine production. These important changes in agricultural land use and livestock production are currently associated to non-climatic drivers, but this dynamic might be strongly affected by the consequences of climate change and variability, with negative socio-economic impacts for the whole region.